کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304982 | 974864 | 2007 | 5 صفحه PDF | دانلود رایگان |
Depending on the solvents used for crystallization, silver nitrate and the flexible dithioether-type ligand incorporating piperazine diamide [L: 1,4-bis((cyclohexylthio)acetyl)piperazine] readily formed two distinct types of 2D (1) and 3D (2) coordination polymers with identical formula [Ag2(NO3)2L]n. The preparation and structural characterisation of 1 and 2 are reported as an example for the supramolecular isomerism.
Depending on the solvents used for crystallization, silver nitrate and the flexible dithioether-type ligand incorporating piperazine diamide [L: 1,4-bis((cyclohexylthio)acetyl)piperazine] readily formed two distinct types of 2D (1) and 3D (2) coordination polymers with identical formula [Ag2(NO3)2L]n. The preparation and structural characterisation of 1 and 2 are reported as an example for the supramolecular isomerism.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 10, Issue 3, March 2007, Pages 313–317