Double HCl elimination and configuration change in the square-planar palladium complex trans-[{(Ph2PC6H4CONH)2C6H4}PdCl2] under Suzuki conditions: Isolation and molecular structure of cis-[{(Ph2PC6H4CON)2C6H4}Pd]

The trans-configurated square-planar palladium complex trans-[{(Ph2PC6H4CONH)2C6H4}PdCl2] (1), which catalyzes the Suzuki cross copuling of 4-bromotoluene with phenylboronic acid, was found to react with potassium carbonate in toluene at 90 °C (Suzuki conditions) to give cis-[{(Ph2PC6H4CON)2C6H4}Pd] (2). Both complexes 1 and 2 show approximately the same catalytic performance for Suzuki reactions, suggesting 2 to be the catalytically active species.