کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1305068 | 974869 | 2006 | 4 صفحه PDF | دانلود رایگان |

The reaction of the molybdenum–dinitrosyl complexes with PPh3, using 2-pyrimidinethiolate (pymt) or 2-pyridinethiolate (pyt) as a thiolate ligand, was found to produce a dinuclear complex [{(ON)MoL2}2(μ-OH)2] (1) (L = pymt or pyt) and Ph3PO. In addition, the first reported example of a mixed valence molybdenum–nitrosyl tetranuclear complex, [Ph3POH]2[{(ON)Mo(pymt)2}2(μ-MoO4)2] (2), was produced by the reaction of 1(pymt) with Ph3PO. This is the first published nitrosyl complex containing both tetraoxomolybdate and thiolato ligands. The molybdenum and bridging oxygen atoms formed a novel eight-membered ring with a central porous structure.
The reaction of the molybdenum–dinitrosyl complexes with PPh3, using 2-pyrimidinethiolate (pymt) or 2-pyridinethiolate (pyt) as a thiolate ligand, was found to produce a dinuclear complex [{(ON)MoL2}2(μ-OH)2] (1) (L = pymt or pyt) and Ph3PO. In addition, the first reported example of a mixed valence molybdenum–nitrosyl tetranuclear complex, [Ph3POH]2[{(ON)Mo(pymt)2}2(μ-MoO4)2] (2), was produced by the reaction of 1(pymt) with Ph3PO. This is the first published nitrosyl complex containing both tetraoxomolybdate and thiolato ligands. The molybdenum and bridging oxygen atoms formed a novel eight-membered ring with a central porous structure.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 9, Issue 2, February 2006, Pages 183–186