A novel 2D framework containing nanometer channel by significant hydrogen bonds and π–π interactions

A novel 2D framework containing nanometer channel, Cd(HA)2(H2O)2 (1) (H2A: 9-ethylcarbazole-3,6-dicarboxylic acid) has been prepared by hydrothermal synthesis. Single crystal X-ray analysis has revealed that the 2D framework of the title compound is formed by significant hydrogen bonds and π–π interactions. The solid state fluorescent property was investigated at room temperature.

2D structure of 1 is formed by intermolecular hydrogen bond O-H⋯O and π–π interactions. The solid state fluorescent property was investigated at room temperature.Figure optionsDownload as PowerPoint slide