کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1305176 | 974875 | 2006 | 5 صفحه PDF | دانلود رایگان |
A first-row transition metal assisted modification of the Michaelis–Arbuzov rearrangement has been discovered that allows the reaction to take place under ambient conditions using a mild phosphine nucleophile. This reaction has been used as a novel synthetic strategy for the assembly of P–C bonds in typically difficult to construct 3-methylpyridyl substituted phosphine and phosphonium ligands. Metal complexes of these ligands were characterized crystallographically. One of the products also contains the previously unknown pyridylFeCl3- species.
A first-row transition metal assisted modification of the Michaelis–Arbuzov rearrangement has been discovered that allows the reaction to take place under ambient conditions using a mild phosphine nucleophile and has been used as a novel method for the construction of a new P–C bond.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 9, Issue 4, April 2006, Pages 418–422