کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1305213 | 1498920 | 2016 | 4 صفحه PDF | دانلود رایگان |
Two tin compounds [Sn(nBu)2(Ln)], where L1{O(C6H4-2-NC(H)C6H4-2′-O)2}2 − and L2{O(C6H4-2-C(H)NC6H4-2′-O)2}2 − enclosing five electron donors in an [ON2O2] core, were synthesized and structurally characterized by infrared and NMR spectroscopy and by single crystal X-ray crystallographic studies at room temperature. The hepta-coordinate geometry around the Sn centers is achieved through the bonding of two monodentate n-butyl groups and the coordination of the pentadentate Ln ligands, where the [ON2O2] core is forming a pentagonal base. The two types of oxygen atoms displayed different bonding situations around the Sn atom. DFT calculations with Gaussian 09 using PBEPBE/6-31G**/SDD level were carried out for both compounds. The topological analysis indicated that bond critical points are present along the SnOether direction.
Journal: Inorganic Chemistry Communications - Volume 70, August 2016, Pages 75–78