کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1305739 | 975048 | 2011 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A unique 3-D chiral Zn(II) coordination framework with 1,2,3-benzenetricarboxyl and 4,4′-bipyridyl tectons showing 4-connected self-penetrating network and helical character A unique 3-D chiral Zn(II) coordination framework with 1,2,3-benzenetricarboxyl and 4,4′-bipyridyl tectons showing 4-connected self-penetrating network and helical character](/preview/png/1305739.png)
Hydrothermal reaction of Zn(II) acetate, 4,4′-bipyridyl (bpy) and 1,2,3-benzenetricarboxylic acid (H3bta) results in a 3-D coordination framework {[Zn4(bta)2(Hbta)(bpy)3](H2O)3}n (1), which shows the self-penetrating net with a new 4-connected topological prototype and chiral helical character.
Hydrothermal reaction of Zn(II) acetate, 4,4′-bipyridyl (bipy) and 1,2,3-benzenetricarboxylic acid (H3bta) results in a 3-D coordination framework, which shows the self-penetrating net with a new 4-connected topological prototype and chiral helical character.Figure optionsDownload as PowerPoint slideResearch Highlights
► A self-penetrating 4-connected coordination framework with chiral helical features from Zn(II) and mixed organic ligands of H3bta and bipy.
► Complex 1 represents a unique self-penetrating supramolecular pattern with the unprecedented (4.62.83)2(42.62.82) net topology.
► Homochiral crystalline packing of right-handed or left-handed helices was found in the title complex.
Journal: Inorganic Chemistry Communications - Volume 14, Issue 10, October 2011, Pages 1584–1587