کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1305904 | 975053 | 2011 | 4 صفحه PDF | دانلود رایگان |
An iridium(III) pyrimidine complex Ir(NDMP)2acac (NDMP = 2-(2-naphthyl)-4,6-dimethylpyrimidine, acac = acetylacetonate) was synthesized and characterized by 1H NMR, 13C NMR, MALDI-TOF mass spectrometry and elemental analysis. An unexpected mononuclear complex Ir(NDMP)2(Cl)(H2O) was obtained in the process of preparing the Cl-bridged dimer [Ir(NDMP)2Cl]2. The crystal structures of these complexes were determined by X-ray single crystal diffraction and contrastively studied. The photoluminescence spectrum of Ir(NDMP)2acac exhibits a yellow emission at 560 nm. The HOMO and LUMO energy levels of Ir(NDMP)2acac were calculated to be − 5.14 eV and − 2.80 eV respectively.
A new cyclometalated iridium(III) pyrimidine complex Ir(NDMP)2acac was synthesized and characterized. A mononuclear complex Ir(NDMP)2(Cl)(H2O) was found in the synthesis process of the Cl-bridged dimer [Ir(NDMP)2Cl]2, and the target product Ir(NDMP)2acac can be prepared from either Ir(NDMP)2(Cl)(H2O) or [Ir(NDMP)2Cl]2. (NDMP)2acac is a promising yellow phosphorescent material for OLED.Figure optionsDownload as PowerPoint slideResearch Highlights
► A new cyclometalated iridium(III) pyrimidine complex Ir(NDMP)2acac was synthesized.
► Ir(NDMP)2acac was synthesized from either [Ir(NDMP)2Cl]2 or Ir(NDMP)2(Cl)(H2O).
► The crystal structures of all these iridium(III) complexes were studied.
► Ir(NDMP)2acac is a promising phosphorescent material for OLEDs.
Journal: Inorganic Chemistry Communications - Volume 14, Issue 1, January 2011, Pages 316–319