کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1305946 | 975057 | 2010 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Syntheses, structures, and luminescent properties of zinc(II) complexes assembled with aromatic polycarboxylate and 1,3-bis(1,2,4-triazol-1-yl)propane Syntheses, structures, and luminescent properties of zinc(II) complexes assembled with aromatic polycarboxylate and 1,3-bis(1,2,4-triazol-1-yl)propane](/preview/png/1305946.png)
Three new coordination compounds, {[Zn(btrp)(ip)]∙2H2O}n (1), {[Zn(btrp)(hip)]∙2H2O}n (2), and {[Zn1.5(btrp)(btc)(H2O)]∙H2O}n (3) (btrp = 1,3-bis(1,2,4-triazol-1-yl)propane, H2ip = isophthalate, H2hip = 5-hydroxy isophthalate, H3btc = benzene-1,3,5-tricarboxylic acid) have been prepared via solvothermal method and characterized by single crystal X-ray diffraction and elemental analysis. 1 possesses 2D (4. 4) net framewok. 2 is also a 2D infinite layer framework, and the resulting 2D structure is interconnected by hydrogen-bond and π…π interactions to lead to a 3D supramolecular architecture. 3 exhibits a novel 2D framework with three nonequivalent points, {5.62}{52.6}{54.82}. The fluorescence properties of 1–3 have been studied at room temperature.
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Journal: Inorganic Chemistry Communications - Volume 13, Issue 12, December 2010, Pages 1497–1500