کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1306069 975061 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, structures and properties of Cu and Cd complexes with 1,10-phenanthroline
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, structures and properties of Cu and Cd complexes with 1,10-phenanthroline
چکیده انگلیسی

Three new Cu and Cd complexes, namely [Cu(phen)(isca)(EtOH)] (1),[Cu(phen)2(HCOOH)] (2) and [Cd(phen)Cl2](3) (phen = 1, 10-phenanthroline, isca = isophthalic acid) have been synthesized, which are characterized by elemental analysis, infrared spectrum and x-ray crystal diffraction. While strong hydrogen bonds play central roles in the formation of the 3D structure, the combined influence of the weak interactions such as C-H···O bonds, C-H···π and lone pair···π interactions are also evident in the structures. The preliminary investigation on the thermal and fluorescence property of the complexes are presented.

Graphical AbstractThe combined influence of the weak interactions such as C-H···O bonds, π···π and lone pair···π interactions play important roles in the formation of the structures.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 13, Issue 5, May 2010, Pages 645–648
نویسندگان
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