کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306069 | 975061 | 2010 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, structures and properties of Cu and Cd complexes with 1,10-phenanthroline Synthesis, structures and properties of Cu and Cd complexes with 1,10-phenanthroline](/preview/png/1306069.png)
Three new Cu and Cd complexes, namely [Cu(phen)(isca)(EtOH)] (1),[Cu(phen)2(HCOOH)] (2) and [Cd(phen)Cl2](3) (phen = 1, 10-phenanthroline, isca = isophthalic acid) have been synthesized, which are characterized by elemental analysis, infrared spectrum and x-ray crystal diffraction. While strong hydrogen bonds play central roles in the formation of the 3D structure, the combined influence of the weak interactions such as C-H···O bonds, C-H···π and lone pair···π interactions are also evident in the structures. The preliminary investigation on the thermal and fluorescence property of the complexes are presented.
Graphical AbstractThe combined influence of the weak interactions such as C-H···O bonds, π···π and lone pair···π interactions play important roles in the formation of the structures.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 13, Issue 5, May 2010, Pages 645–648