کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306124 | 975067 | 2009 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Construction and photoluminescence properties of two novel zinc(II) and cadmium(II) benzyl-tetrazole coordination polymers Construction and photoluminescence properties of two novel zinc(II) and cadmium(II) benzyl-tetrazole coordination polymers](/preview/png/1306124.png)
Two new d10 coordination polymers, Zn(Beta)2 (1) and Cd2(Beta)3Cl(H2O) (2) (Hbeta = 5-benzyl-tetrazole) have been synthesized by the in situ [3 + 2] cycloaddition reaction of 5-benzylacetonitrile, sodium azide and MCl2 [M = Zn (1); M = Cd (2)] under hydrothermal condition. Complex 1 is a coordination polymer comprised of numerous mildly undulated two-dimensional (2D) layers with a (4, 4) topological network; while complex 2 is a 3D coordination framework constructed from the interconnection of various helical chains through cadmium–chlorine bridges. Furthermore, the luminescence properties of two complexes have been investigated.
Two new d10 coordination polymers, Zn(Beta)2 (1) and Cd2(Beta)3Cl(H2O) (2) (Hbeta = 5-benzyl-tetrazole) have been synthesized by the in situ [3 + 2] cycloaddition reaction of 5-benzylacetonitrile, sodium azide and MCl2 [M = Zn (1); M = Cd (2)] under hydrothermal condition. Complex 1 is a coordination polymer comprised of numerous mildly undulated two-dimensional (2D) layers with a (4, 4) topological network; while complex 2 is a 3D coordination framework constructed from the interconnection of various helical chains through cadmium–chlorine bridges.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 12, Issue 12, December 2009, Pages 1200–1203