1-D networks formed by metal⋯sulfur van der Walls contacts: Novel tetrazole–thiolato Pd(II) and Pt(II) complexes

Pd(II)– and Pt(II)–azido complexes, [M(N3)(PMe3)2(C–L)] {LH = 2-(2′)-thienyl pyridine; M = Pd (1), Pt(2)}, which contain σ-bonded heterocycles (L), were treated with aryl isothiocyanate (Me2C6H3–NCS) to afford the corresponding Pd(II) and Pt(II) tetrazole–thiolato complexes, trans-{M[SCN4(2,6-Me2C6H3)](PMe3)2(C–L)} {M = Pd (3), Pt (4)}. Complexes 3 and 4 have a 1-D helical network formed by the intermolecular M⋯S van der Waals contacts.

Metal–azido complexes, [M(N3)(PMe3)2(C–L)] {LH = 2-(2′)-thienyl pyridine; M = Pd, Pt} were treated with Me2C6H3–NCS to afford the corresponding tetrazole–thiolato complexes, trans-{M[SCN4(2,6-Me2C6H3)](PMe3)2(C–L)}.Figure optionsDownload as PowerPoint slide