3D Ln–Ag (Ln = Nd; Eu) coordination polymers based on isonicotinate and oxalate ligands: Synthesis, crystal structures and luminescence

The self-assembly of isonicotinic acid with metal salts under hydrothermal conditions obtained two new 4d–4f coordination polymers, LnAg(OX)(IN)2·H2O (Ln = Nd (1); Eu (2), OX = oxalic acid, IN = isonicotinic acid). The 3D isostructural complexes 1 and 2 are constructed by the assembly of 2D layers, which are built by carboxylate groups of isonicotinic acid and oxalate ligands coordinating to metal centers, with 1D linear linkers completed by silver ions. Furthermore, the luminescent property of complex 2 was investigated.

Two novel isostructural 3D 4d–4f coordination polymers, LnAg(OX)(IN)2·H2O (Ln = Nd (1); Eu (2), OX = oxalic acid, IN = isonicotinic acid), were prepared under hydrothermal condition and characterized by X-ray single-crystal diffraction, elemental analysis, FT-IR, TGA and photoluminescence measurements.Figure optionsDownload as PowerPoint slide