کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1306466 | 975091 | 2008 | 4 صفحه PDF | دانلود رایگان |

Two novel coordination polymers containing Cd(II) and Co(II) metals, connected via 1,1′-(2,2′-oxybis(ethane-2,1-diyl))bis(1H-imidazole) (L) ligand, have been synthesized. Compound [Cd(L)2(p-BDC)] · 2H2O (1) (p-BDC = 1,4-benzenedicarboxylate anion) is a three-dimensional interdigitated supramolecular architecture. Compound [Co(L)(BTCA)0.5] (2) (BTCA = 1,2,3,4-butanetetracarboxylate anion) possesses a unique (3,4)-connected 3D framework with (83)2(85 · 10) topology.
This work describes the hydrothermal syntheses and characterizations of two novel coordination polymers [Cd(L)2(p-BDC)] · 2H2O (1) and [Co(L)(BTCA)0.5] (2), in which L is a novel bis(imidazole) ligand, 1,1′-(2,2′-oxybis(ethane-2,1-diyl))bis(1H-imidazole). The topology analyses for these compounds and the luminescent property for 1 are discussed.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 11, Issue 10, October 2008, Pages 1155–1158