کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306756 | 975102 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective and sensitive recognition of hexafluorophosphate via an unusual equilibrium between a cationic square host and a PF6- guest
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Hyper-selective and -sensitive recognition of hexafluorophosphate via a rigid molecular square has been carried out in solution. The equilibrium of [Pd(Me4en)(Isoni)(PF6)1/4]4(PF6)3/[Pd(Me4en)(Isoni)]4(PF6)4 (Me4en = N,N,N′,N′-tetramethylethylenediamine; Isoni = isonicotinate) has been monitored via a suitable combination of electrostatic interactions and size effects between a cationic square host and a PF6- guest.
The equilibrium of [Pd(Me4en)(Isoni)(PF6)1/4]4(PF6)3/[Pd(Me4en)(Isoni)]4(PF6)4 (Me4en = N,N,N′,N′-tetramethylethylenediamine; Isoni = isonicotinate) has been monitored via electrostatic interactions and size effects between a cationic square host and a PF6- guest.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 10, Issue 9, September 2007, Pages 967–970
Journal: Inorganic Chemistry Communications - Volume 10, Issue 9, September 2007, Pages 967–970
نویسندگان
In Sung Chun, Sung Jin Moon, Young Mee Na, Young-A. Lee, Kyung Ho Yoo, Ok-Sang Jung,