کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1313925 1499357 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Halofluorination of alkenes mediated by 1,1,3,3,3-pentafluoropropene-diethylamine adduct
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Halofluorination of alkenes mediated by 1,1,3,3,3-pentafluoropropene-diethylamine adduct
چکیده انگلیسی

1,1,3,3,3-Pentafluoropropene-diethylamine complex (PFPDEA) has been found useful as a fluoride source in halofluorination reactions of various olefins. Reactions proceeded with PFPDEA and N-halosuccinimide (NXS, X = Br, I) or 1,3-dibromo-5,5-dimethylhydantoin (DBH), as sources of electrophilic halogens, in a regioselective manner.

1,1,3,3,3-Pentafluoropropene-diethylamine complex (PFPDEA) has been found useful as a fluoride source in halofluorination reactions of various olefins. Reactions proceeded with PFPDEA and N-halosuccinimide (NXS, X = Br, I) or 1,3-dibromo-5,5-dimethylhydantoin (DBH), as sources of electrophilic halogens, in a regioselective manner.Figure optionsDownload as PowerPoint slideHighlights
► Pentafluoropropene-diethylamine adduct is an efficient reagent in halofluorination as a source of nucleophilic fluoride.
► The halofluorination is highly regioselectivite (formation of Markovnikov products).
► The halofluorination is stereospecific in an anti-sence.
► The method allows introduction of fluorine into alkenes under mild conditions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 143, November 2012, Pages 287–291
نویسندگان
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