کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1314000 | 1499353 | 2013 | 4 صفحه PDF | دانلود رایگان |
Two new Schiff base compounds, tailed by the fluoroalkoxy, were synthesized in a three-step process. Those supramolecular structures constructed by hydrogen bonding show good liquid crystal properties with higher clear points and wider mesomorphic phase ranges than other analogs containing a terminal alkoxy chain. Investigation of the optical textures by polarizing microscopy reveals that terminal fluorinated substituents convert the nematic phase of supramolecular hydrogen-bonding complexes with terminal alkoxy chains into the smectic A phase of those with terminal fluoroalkoxy chains.
Two new schiff base compounds, with fluoroalkoxy as the terminal chains, were synthesized in three steps. Their supramolecular hydrogen bonding complexes show smectic A phase with higher clear points and wider mesomorphic phase ranges than those of the analogs with a terminal alkoxy chain.Figure optionsDownload as PowerPoint slideHighlights
► We synthesized new schiff base with fluoroalkoxy as the terminal chains.
► The corresponding supramolecular liquid crystals show good mesomorphic properties.
► Wide mesomorphic phase ranges and high order were found.
► The corresponding supramolecular liquid crystals show smectic A phase.
► However, the analogs with alkoxy terminal chains show nematic phase.
Journal: Journal of Fluorine Chemistry - Volume 147, March 2013, Pages 36–39