کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1314269 | 975957 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Elemental fluorine. Part 24.[1]: Fluorination of ethers by fluorine and Selectfluor
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
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چکیده انگلیسی
Reactions of dialkyl ethers with either fluorine or Selectfluor™ led to the formation of unusual difluorinated polyether products in modest yields. A mechanism involving initial fluorination of the site adjacent to ether oxygen followed by elimination of hydrogen fluoride, reaction of the generated enol system with a further equivalent of fluorinating agent giving an oxonium system which reacts with water during aqueous work-up to lead eventually to the products observed, is suggested.
Reactions of dialkyl ethers with either fluorine or Selectfluor™ led to the formation of unusual difluorinated polyether products in modest yields.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 131, Issue 9, September 2010, Pages 933–936
Journal: Journal of Fluorine Chemistry - Volume 131, Issue 9, September 2010, Pages 933–936
نویسندگان
Richard D. Chambers, Takashi Okazoe, Graham Sandford, Emmanuelle Thomas, Jelena Trmcic,