کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1314344 | 975962 | 2010 | 6 صفحه PDF | دانلود رایگان |
The reactions of fluoroalkanesulfonyl azides with pyrrole and its derivatives were studied. The reaction proceeded smoothly under mild conditions to give the 3-(fluoroalkanesulfonamido) pyrroles in good yield. The electron donating groups on the pyrrole core accelerated the reaction, while the electron withdrawing groups decelerated it. All the products were fully characterized by spectrum methods, and one of the products was further confirmed by X-ray diffraction analysis. A possible reaction mechanism for these reactions was proposed.
The reactions of fluoroalkanesulfonyl azides with pyrrole and its derivatives were studied. The reaction proceeded smoothly under mild conditions to give the 3-(fluoroalkanesulfonamido) pyrroles in good yield. The electron donating groups on the pyrrole core accelerated the reaction, while the electron withdrawing groups decelerated it. All the products were fully characterized by spectrum methods, and one of the products was further confirmed by X-ray diffraction analysis. A possible reaction mechanism for these reactions was proposed.Figure optionsDownload as PowerPoint slide
Journal: Journal of Fluorine Chemistry - Volume 131, Issue 8, August 2010, Pages 867–872