کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1314493 | 1499355 | 2013 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective introduction of fluorine atoms to the tert-carbons of functionalized adamantanes by BrF3
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Selective introduction of fluorine atoms to the tert-carbons of functionalized adamantanes by BrF3 Selective introduction of fluorine atoms to the tert-carbons of functionalized adamantanes by BrF3](/preview/png/1314493.png)
چکیده انگلیسی
⺠Fluorination of functionalized adamantanes was performed with BrF3. ⺠Three to two fluorine atoms were selectively introduced to their tert-carbons. ⺠From methyl adamantane-1-carboxylate, methyl 3,5,7-trifluoroadamantane-1-carboxylate was selectively formed. ⺠Unexpected reactions, such as fluorination of carbonyl group, also occurred.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 145, January 2013, Pages 128-131
Journal: Journal of Fluorine Chemistry - Volume 145, January 2013, Pages 128-131
نویسندگان
Toru Shishimi, Shoji Hara,