کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1314639 | 1499360 | 2012 | 4 صفحه PDF | دانلود رایگان |
Reaction of [(dippe)NiI2] (dippe = 1,2-bis(diisopropylphosphino)ethane) with excess [NMe4][SCF3] led to the formation of [(dippe)Ni(SCF3)2] (1) in 92% isolated yield. Complex 1 has been structurally characterized, and the data provides the first experimentally determined bond parameters of a nickel–trifluoromethylthiolate complex. The molecule lies on a two-fold axis, with nickel-phosphorus bonds of 2.1828(4) Å and nickel-sulfur bonds of 2.2395(4) Å. Density functional theory (DFT) calculations predict that the highest occupied molecular orbital (HOMO) is sulfur-centered and the lowest unoccupied molecular orbital (LUMO) is nickel-centered.
Reaction of [(dippe)NiI2] (dippe = 1,2-bis(diisopropylphosphino)ethane) with excess [NMe4][SCF3] led to the formation of [(dippe)Ni(SCF3)2] (1) in 92% isolated yield. Complex 1 has been structurally characterized, and the data provides the first experimentally determined bond parameters of a nickel-trifluoromethylthiolate complex. The molecule lies on a two-fold axis, with nickel–phosphorus bonds of 2.1828(4) Å and nickel–sulfur bonds of 2.2395(4) Å. Density functional theory (DFT) calculations predict that the highest occupied molecular orbital (HOMO) is sulfur-centered and the lowest unoccupied molecular orbital (LUMO) is nickel-centered.Figure optionsDownload as PowerPoint slideHighlights
► Reaction of [(dippe)NiI2] with excess [NMe4][SCF3] led to the formation of [(dippe)Ni(SCF3)2].
► [(dippe)Ni(SCF3)2] has been structurally characterized.
► Density functional theory calculations predict that the highest occupied molecular orbital of [(dippe)Ni(SCF3)2] is sulfur-centered and the lowest unoccupied molecular orbital is nickel-centered.
► Charge distributions on a metal–SCF3 complex are much different than a metal–OCF3 one.
Journal: Journal of Fluorine Chemistry - Volume 140, August 2012, Pages 112–115