Size-dependent upconversion luminescence in YF3:Yb3+/Tm3+ nanobundles

The upconversion luminescent properties of YF3:Yb3+(20%)/Tm3+(1%) nanobundles with different sizes (240–500 nm in length) were studied under 980-nm excitation. Ultraviolet (1I6 → 3F4/3H6 and 1D2 → 3H6), blue (1D2 → 3F4 and 1G4 → 3H6), red (1D2 → 3H4, 1G4 → 3F4, and 3F3 → 3H6), and near infrared (3H4 → 3H6) emissions were observed. The results indicated that the relative intensity of the ultraviolet to the blue as well as the blue to the near infrared increased with decreasing the size of nanobundles. Especially, the position of the dominant red emission peak varied with the size of nanobundles. As the length of nanobundles increased to 500 nm, unusual 3F3 → 3H6 transition was observed, which was theoretically explained considering the decrease of the nonradiative transition rate of 3F3 → 3H4.

TEM images of YF3:Yb3+/Tm3+ nanobundles aged for different time: (a) 24 h, (b) 48 h, and (c) 72 h.Figure optionsDownload as PowerPoint slide