کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1314887 975990 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, characterization and properties of a novel fluorinated methacrylate polymer
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, characterization and properties of a novel fluorinated methacrylate polymer
چکیده انگلیسی

A fluorinated monomer of 2-(2,2,2-trifluoroethoxy)ethyl methacrylate (FEMA) was prepared by a “one pot” process and then a novel fluorinated methacrylate polymer, poly[2-(2,2,2-trifluoroethoxy)ethyl methacrylate] (PFEMA), was successfully synthesized via miniemulsion polymerization using cetyltrimethyl ammonium bromide (CTAB) as emulsifier, hexadecane (HD) as co-stabilizer and 2,2′-azobisisobutyronitrile (AIBN) as initiator. The chemical structure of PFEMA was characterized by FT-IR, 1H NMR and 19F NMR. GPC results show that the number average molecular weight (Mn) of PFEMA was as high as 8.5 × 105 g/mol and the polydispersity index (PDI) was only 1.3. SEM and DLS characterizations showed that the morphology of PFEMA latex was uniform spheres with the diameter of about 110–125 nm. It was also found that PFEMA has high thermo-stability (Td > 200 °C), low glass transition temperature (Tg = 13.0 °C), and nice hydrophobicity (θwater = 99.9°). Comparison studies on PFEMA and poly(2,2,2-trifluoroethyl methacrylate) show that an introduced functional group (–CH2CH2O–) has a significant effect on lowering Tg and improving hydrolysis resistance without impairing surface properties.

2-(2,2,2-Trifluoroethoxy)ethyl methacrylate (FMA) was synthesized using a “one pot” process. Novel and stable poly[2-(2,2,2-trifluoroethoxy)ethyl methacrylate] (PFEMA) latex was successfully prepared by miniemulsion polymerization.Figure optionsDownload as PowerPoint slideHighlights
► 2-(2,2,2-Trifluoroethoxy)ethyl methacrylate was synthesized.
► Its polymer latex was prepared by miniemulsion polymerization.
► The structures of the fluorinated monomer and its polymer were characterized.
► The properties of the polymer were also studied.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 132, Issue 11, November 2011, Pages 915–919
نویسندگان
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