کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1315074 | 1499363 | 2012 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
2-Cyano-6-(trifluoromethyl)-4H-pyran-4-one: A novel versatile CF3-containing building block
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A highly electrophilic pyrone, 2-cyano-6-(trifluoromethyl)-4H-pyran-4-one, was synthesized. The reactions of this cyanopyrone with N-nucleophiles can proceed with or without substitution of the cyano group to give a wide range of novel trifluoromethylated compounds. An oxindole derivative was synthesized from a phenylhydrazide using unusual (acidic) conditions.
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► 2-Cyano-6-(trifluoromethyl)-4H-pyran-4-one was synthesized.
► Various trifluoromethylated compounds were prepared on the base of 2-cyano-6-(trifluoromethyl)-4H-pyran-4-one.
► An oxindole derivative was synthesized from a phenylhydrazide using unusual (acidic) conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 137, May 2012, Pages 22–26
Journal: Journal of Fluorine Chemistry - Volume 137, May 2012, Pages 22–26
نویسندگان
Boris I. Usachev, Dmitrii L. Obydennov, Gerd-Volker Röschenthaler, Vyacheslav Ya. Sosnovskikh,