کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1315085 1499363 2012 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A new entry for the oxidation of fluoroalkyl-substituted methanol derivatives: Scope and limitation of the organoiodine(V) reagent-catalyzed oxidation
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A new entry for the oxidation of fluoroalkyl-substituted methanol derivatives: Scope and limitation of the organoiodine(V) reagent-catalyzed oxidation
چکیده انگلیسی

Oxidation of various fluoroalkyl-substituted methanol derivatives under the influence of a catalytic amount of sodium 2-iodobenzenesulfonate and Oxone® in CH3CN or CH3NO2 was investigated in detail. The efficiency of the newly developed oxidation was also evaluated by comparison to other oxidations, such as Dess–Martin, PDC, and Swern oxidation.

The hypervalent iodine(V)-catalyzed oxidation of fluorinated alcohols to the corresponding ketones was developed as the alternative to Dess–Martin oxidation.Figure optionsDownload as PowerPoint slideHighlights
► The hypervalent iodine(V)-catalyzed oxidation for fluorinated alcohols was established.
► Various fluorinated alcohols can be converted into the corresponding ketones in high yields.
► This system is superior to PDC, Swern oxidations, and comparable to Dess–Martin oxidation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 137, May 2012, Pages 99–104
نویسندگان
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