کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1315104 976003 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermal chlorofluorination of propyne and propadiene II
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Thermal chlorofluorination of propyne and propadiene II
چکیده انگلیسی

Propyne and propadiene have been previously reported to readily undergo vapor phase catalyzed chlorofluorination at temperatures to 285 °C to form C3F4Cl4 mixtures that are primarily CFCl2–CF2–CFCl2. Continued fluorination at temperatures up to 485 °C produce the rearranged C3F6Cl2 isomers CF3–CCl2–CF3 and CF2Cl–CFCl–CF3.

Propyne and propadiene have been previously reported to readily undergo vapor phase catalyzed chlorofluorination at temperatures to 285 °C to form C3F4Cl4 mixtures that are primarily CFCl2–CF2–CFCl2. Continued fluorination at temperatures up to 485 °C produced the rearranged C3F6Cl2 isomers CF3–CCl2–CF3 and CF2Cl–CFCl–CF3. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 128, Issue 5, May 2007, Pages 552–556
نویسندگان
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