کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1315198 1499368 2009 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical fluorination (Simons process) – A powerful tool for the preparation of new conducting salts, ionic liquids and strong Brønsted acids
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Electrochemical fluorination (Simons process) – A powerful tool for the preparation of new conducting salts, ionic liquids and strong Brønsted acids
چکیده انگلیسی

Electrochemical fluorination (Simons process) provides a cheap commercial access to a series of tris(perfluoroalkyl)diflurophosphoranes. These substances are convenient starting material for the preparation of various fluoro-chemicals. The synthesis of new conducting salts and ionic liquids with perfluoroalkyl-fluorophosphate (FAP) and perfluoroalkyl-phosphinate anions is described. FAP ionic liquids exhibit excellent hydrolytic stability, low viscosity and high electrochemical and thermal stability. Organic and inorganic salts with FAP anions possess high electrochemical stability and conductivity that makes them attractive for application in several electrochemical devices (Li-ion batteries, super-capacitors, etc.). The possible application of H[(RF)3PF3] (HFAP), (RF)2P(O)(OH) and (RF)P(O)(OH)2 as components of proton-conducting membranes is discussed.

Electrochemical fluorination (Simons process) provides a cheap commercial access to a series of tris(perfluoroalkyl)diflurophosphoranes. These substances are convenient starting material for the preparation of various fluoro-chemicals.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 130, Issue 12, December 2009, Pages 1183–1191
نویسندگان
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