Stereoselective synthesis of 4-fluoro-1,3-alkadienylboronates and their application in the stereoselective synthesis of fluoropolyenes

(1E,3E)- and (1E,3Z)-4-fluoro-1,3-alkadienylboronates were stereoselectively prepared by the Heck-reaction of a vinylboronate with (E)- or (Z)-2-fluoro-1-alkenyliodonium salts, and applied to the Suzuki-Miyaura coupling reaction for the synthesis of fluoropolyenes.