کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1315250 976014 2009 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Coordination chemistry of perfluoroalkylated phosphorus(III) ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Coordination chemistry of perfluoroalkylated phosphorus(III) ligands
چکیده انگلیسی

Palladium(II), platinum(II), rhodium(I), rhodium(III) and iridium(III) complexes of the tridecafluorohexyl-derivatised diphenylethylphosphinite (PPh2OC2H4Rf), phenyldiethylphosphonite {PPh(OC2H4Rf)2}, triethylphosphite {P(OC2H4Rf)3}, triphenylphosphinite (PPh2OC6H4-4-Rf), triphenylphosphonite {PPh(OC6H4-4-Rf)2}, ethyldiphenylphosphine (PPh2C2H4Rf), diethylphenylphosphine {PPh(C2H4Rf)2} and triethylphosphine {P(C2H4Rf)3} ligands are synthesized by conventional ligand displacement and/or halide-bridge cleaved reactions, and their spectroscopic parameters are compared with those for the related ligands lacking the tridecafluorohexyl ponytails.

The spectroscopic parameters of palladium(II), platinum(II), rhodium(I), rhodium(III) and iridium(III) complexes of the tridecafluorohexyl-derivatised ligands (L1–L8), synthesized by conventional ligand displacement and/or halide-bridge cleaved reactions, are compared with those for related ligands lacking the tridecafluorohexyl ponytails.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 130, Issue 10, October 2009, Pages 942–950
نویسندگان
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