کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1315559 | 976044 | 2007 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and polymerization of novel fluorinated acrylates and methacrylates bearing alkoxyl groups derived from radical addition reaction of perfluoroisopropenyl ester
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and polymerization of novel fluorinated acrylates and methacrylates bearing alkoxyl groups derived from radical addition reaction of perfluoroisopropenyl ester Synthesis and polymerization of novel fluorinated acrylates and methacrylates bearing alkoxyl groups derived from radical addition reaction of perfluoroisopropenyl ester](/preview/png/1315559.png)
چکیده انگلیسی
Radical addition of 2-benzoxypentafluoropropene [CF2C(CF3)OCOC6H5] (BPFP) with alcohols such as ethanol and 2-propanol was investigated to afford fluorinated alcohols. Radical addition of BPFP with cyclic ethers such as tetrahydrofuran, 1,3-dioxolane and tetrahydropyran was also achieved to afford addition products followed by hydrolysis to yield fluorinated alcohols possessing cyclic structures. Novel fluoroalkyl acrylates and methacrylates were synthesized from the fluorinated alcohols with (meth)acryloyl chlorides. Radical polymerization of the fluoroalkyl (meth)acrylates yielded polymers of 1.2Â ÃÂ 105 as the highest molecular weight.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 128, Issue 8, August 2007, Pages 965-970
Journal: Journal of Fluorine Chemistry - Volume 128, Issue 8, August 2007, Pages 965-970
نویسندگان
Tadashi Narita, Yoshiomi Sakuragi, Hiroaki Yabata, Daisuke Kimura, Hiroshi Hamana,