کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1315660 1499369 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel synthetic approach to fluorine-containing acetylenic compounds based on Nicholas reaction
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A novel synthetic approach to fluorine-containing acetylenic compounds based on Nicholas reaction
چکیده انگلیسی

The fluorine-containing dicobalthexacarbonyl complex, prepared readily from γ-fluoroalkylated propargyl acetates and Co2(CO)8, reacted smoothly with various nucleophiles at the propargylic position, followed by oxidative decomplexation under the influence of Fe(NO3)3, to afford fluoroalkylated alkynes bearing various types of alkyl side chains in good to high yields.

Various fluorine-containing dicobalthexacarbonyl complexes, prepared readily from γ-fluoroalkylated propargyl acetates and Co2(CO)8, reacted smoothly with various nucleophiles at the propargylic position, followed by oxidative decomplexation under the influence of Fe(NO3)3, to afford fluoroalkylated alkynes bearing various types of alkyl side chains in good to high yields. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 127, Issues 4–5, May 2006, Pages 510–518
نویسندگان
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