کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1315689 976059 2006 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Fluoropropenoates as dienophiles in the Diels–Alder reaction
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Fluoropropenoates as dienophiles in the Diels–Alder reaction
چکیده انگلیسی

Several fluorinated alkenes were prepared from known ethyl (R)-2-fluoro-4,5-dihydroxyisopropylidine-2-pentenoate (1). The fluoroalkenoates were tested as dienophiles with several dienes and showed cycloaddition only with the very reactive diene, 1,3-diphenylisobenzofuran (5). Fluorobutenolide 2 reacted with 5 to produce the endo-syn adduct 9 in a highly stereoselective manner.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 127, Issue 7, July 2006, Pages 861–864
نویسندگان
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