Mesomorphic phase transition behavior of novel triphenylene compounds possessing fluoroalkylated side chains

This report discusses the effect of fluoroalkyl chain on the mesomorphism. Several homologues of novel triphenylene compounds possessing fluoroalkylated side chains were synthesized. Studies of X-ray diffraction, DSC and texture observations by polarized microscope revealed that these homologues show hexagonal columnar (Colh) mesophase. These homologues made columnar mesophase stabilize and the melting point increase, as compared with corresponding alkyloxytriphenylenes. In the case of fluoroalkyloxytriphenylenes possessing fluoromethylene side chains, the increase of the fluoromethylene chain length stabilized columnar mesophase, made the phase transition enthalpy (Colh-Iso) and entropy (Colh-Iso) increase. It is considered that these results are due to the fluorophilic interaction, and that the fluorophilic interaction is important for stabilizing columnar mesophase.

Several homologues of novel triphenylene compounds possessing fluoroalkylated side chains show hexagonal columnar (Colh) mesophase, and make columnar mesophase stabilize, the increase of the fluoromethylene chain length stabilized columnar mesophase. It is considered that the fluorophilic interaction is important for stabilizing columnar mesophase. Figure optionsDownload as PowerPoint slide