کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1315705 976059 2006 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Bromofluorination of olefins using BrF3; an efficient route for fluoroalkenes and fluoroamines
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Bromofluorination of olefins using BrF3; an efficient route for fluoroalkenes and fluoroamines
چکیده انگلیسی

A variety of alkenes and α,β-unsaturated carbonyls were reacted with BrF3 to form vicinal bromofluoro compounds. In most cases, the reactions followed a Markovnikov regioselectivity and anti-addition stereospecifity. They proceeded well even with deactivated olefins in around 70% yield. The bromofluoro compounds served as starting materials for the synthesis of fluoroalkenes and fluoroamines.

A variety of alkenes and α,β-unsaturated carbonyls were reacted with BrF3 to form vicinal bromofluoro compounds. The reactions were regioselctive and anti-addition stereospecific. The bromofluoro compounds served as starting materials for the synthesis of fluoroalkenes and fluoroamines. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 127, Issue 7, July 2006, Pages 962–965
نویسندگان
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