کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1315730 | 976061 | 2006 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A new method for making acyl fluorides using BrF3
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A new method for making acyl fluorides using BrF3 A new method for making acyl fluorides using BrF3](/preview/png/1315730.png)
چکیده انگلیسی
While many carboxylic acids could be converted directly to acyl fluorides by using BrF3, the reaction with acyl chlorides was found to be of a more general nature and yields better results. Surprisingly, reacting t-butyl esters with bromine trifluoride also resulted in acyl fluorides in reasonable yields. The reactions were completed in a few seconds at 0 °C.
Carboxylic acids, acyl chlorides and t-butyl esters can be readily converted to the corresponding acyl fluorides by a fast reaction with BrF3. Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 127, Issue 3, March 2006, Pages 433–436
Journal: Journal of Fluorine Chemistry - Volume 127, Issue 3, March 2006, Pages 433–436
نویسندگان
Or Cohen, Revital Sasson, Shlomo Rozen,