کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1346120 980240 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Stereodifferentiation in the fluorescence of naproxen–arginine salts in the solid state
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Stereodifferentiation in the fluorescence of naproxen–arginine salts in the solid state
چکیده انگلیسی

Three stereoisomeric salts of naproxen (NPX) with arginine (Arg), namely (S)-NPX/(S)-Arg, (R)-NPX/(S)-Arg and (S)-NPX/(R)-Arg, have been prepared, and their fluorescence spectra recorded in solution and in the solid state. While the emission properties in solution did not show significant differences with λmax = 355 nm, τF (MeOH) ca. 11.5 ns and τF (H2O) ca. 9 ns (as NPX/Na), the (R)-NPX/(S)-Arg and (S)-NPX/(R)-Arg solid salts displayed red-shifted fluorescence spectra with maxima at 375 nm and τF = 1.1 ns. By contrast, the behaviour of solid (S)-NPX/(S)-Arg was similar to that of NPX/Na with λmax = 355 nm and τF ca. 5.5 ns. These results are explained based on the X-ray crystal structures and attributed to formation of NPX excimers emitting at longer wavelengths. Accordingly, such excimer emission was also observed in the fluorescence spectrum of a model NPX dyad in solution.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron: Asymmetry - Volume 16, Issue 12, 20 June 2005, Pages 2167–2171
نویسندگان
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