کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1346169 | 980244 | 2012 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
First catalytic enantioselective synthesis of P-stereogenic phosphoramides via kinetic resolution promoted by a chiral bicyclic imidazole nucleophilic catalyst
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel method toward the synthesis of P-stereogenic organophosphorus compounds via kinetic resolution by a catalytic asymmetric phosphorylation through P–N bond formation has been developed. Using a chiral bicyclic imidazole nucleophilic catalyst, chiral phosphoramide compounds were prepared in high conversions and with moderate enantioselectivity. This is also the first example of the catalytic asymmetric synthesis of chiral phosphoramide compounds.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron: Asymmetry - Volume 23, Issue 5, 15 March 2012, Pages 329–332
Journal: Tetrahedron: Asymmetry - Volume 23, Issue 5, 15 March 2012, Pages 329–332
نویسندگان
Shan Liu, Zhenfeng Zhang, Fang Xie, Nicholas A. Butt, Li Sun, Wanbin Zhang,