کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1348927 980375 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The bidentate complexes of (R,R)- and meso-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The bidentate complexes of (R,R)- and meso-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol
چکیده انگلیسی

The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron: Asymmetry - Volume 16, Issue 18, 19 September 2005, Pages 2993–2997
نویسندگان
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