Superhydrophobic concrete surfaces with integrated microtexture

Ultra-High Performance Concrete (UHPC) is characterized by a densely packed mix-design, which can offer attractive surface properties for architectural building facades. A technical challenge for aesthetic applications is the protection against fouling. This work demonstrates that water-repellent concrete can be obtained just after demoulding by replicating the features of micro-pillared moulds made of polydimethylsiloxane (PDMS). Moreover, the negative replica of the microtextured UHPC surface can be used as a master to template for other UHPC samples, constituting a cost-effective route to fabricate large-scale microtextured concrete pieces. The chemical functionalization of UHPC with a low surface energy material is obtained by transferring residues from the PDMS mould or by spraying siloxane-based compounds to form a homogenous surface film. The latter preparation method showed superhydrophobic properties with static contact angles reaching up to 164° and contact angle hysteresis reaching as low as 2.5°. This process enables the manufacture of water-repelling, self-cleaning concrete. Raindrops slide off the concrete surface, carrying debris away.