Gas permeability and electrical conductivity of structural concretes: Impact of pore structure and pore saturation

This paper investigates the gas permeability and the electrical conductivity of structural concretes under different pore saturations. The gas permeability was measured by CemBureau device and the electrical conductivity by alternating current method. The pore structure was characterized by mercury intrusion porosimetry (MIP) and gravimetric methods. The Archie's law is used to interpret the tortuosity of the pore structure. The impact of pore saturation is evaluated through the Van Genuchten-Mualem (VGM) and Kozeny's models. The results show that (1) the global correlation between the gas permeability in dried state and the electrical conductivity in saturated sate is weak; (2) both VGM and Kozeny's models can describe the relative permeability/conductivity, but the VGM model gives more consistent exponents for permeability and conductivity; (3) as the pore gas and liquid phases are both percolated, the gas permeability is correlated to the electrical conductivity for arbitrary pore saturation.