کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
154428 | 456838 | 2016 | 11 صفحه PDF | دانلود رایگان |
• n-Butane oxidation to maleic anhydride in a fixed-bed reactor was simulated.
• A two-dimensional pseudo-heterogeneous model was developed.
• Macro- and micro-pore model of Wakao and Smith was adopted.
• Pore structure parameters of the pellet have impacts on the reactor performance.
• Catalyst pellet with optimal pore structure can improve the yield by several percent.
The effect of catalyst pore structure on n-butane oxidation to maleic anhydride in a fixed-bed reactor was investigated by numerical simulations. The micro- and macro-pore model of Wakao and Smith was applied to model the diffusion–reaction inside the catalyst pellet. The studied pore structure parameters were macro-pore porosity, mean macro-pore diameter and mean micro- pore diameter. A fixed-bed reactor was simulated with a detailed two-dimensional heterogeneous model under typical industrial conditions. Simulation results have demonstrated that the reactor performance is sensitive to the chosen pore structure parameters especially macro-pore porosity and mean micro-pore diameter. A bi-modal catalyst pellet with bigger macro-pores and smaller micro-pores is favored to achieve higher yields of maleic anhydride. This work highlights the potential of improving this process by pore structure optimization.
Journal: Chemical Engineering Science - Volume 142, 13 March 2016, Pages 299–309