کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
155717 456909 2012 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Application of design of experiments in heterogeneous catalysis: Using the isomerization of n-decane for a parameter screening
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Application of design of experiments in heterogeneous catalysis: Using the isomerization of n-decane for a parameter screening
چکیده انگلیسی

The bifunctional isomerization reaction of long-chain n-alkanes to mono-branched isomers is of great interest, as the cold flow properties can be enhanced considerably. In this regard, the isomerization of n-decane on mesoporous bifunctional catalysts was studied using design of experiments.The presented application of an advanced combinatorial design reduced the required experimental testing significantly. The simultaneously varied parameters included pore and channel dimensions of the mesoporous silica support, surface acidity, noble metals and a combination of two additional metals in varying concentrations. The identification of those parameters with highest influence on selectivity and conversion permitted the detailed interpretation and subsequent optimization of the isomerization reaction.The respective support material and its surface acidity are the major driving force for conversion. High acidity increases conversion considerably and does not necessarily diminish selectivity to desired products. Changes concerning the support material may boost activity of the final catalyst sample, yet at the expense of high selectivity. This deleterious effect on selectivity can be counteracted to a considerable degree by adding small amounts of Nb.


► Characterization of isomerization reaction by design of experiments.
► Used experimental design increases efficiency of testing considerably.
► High acidity boosts activity and does not diminish selectivity.
► Niobium doping decreases cracking tendency, thus increasing selectivity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 75, 18 June 2012, Pages 364–375
نویسندگان
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