کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
158257 | 457001 | 2008 | 12 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Determination of the percolation properties and pore connectivity for mesoporous solids using NMR cryodiffusometry Determination of the percolation properties and pore connectivity for mesoporous solids using NMR cryodiffusometry](/preview/png/158257.png)
Using a model disordered mesoporous solid with a spatial arrangement of pore sizes analogous to a macroscopic ‘ink-bottle’, it has been shown that the hysteresis observed in NMR cryoporometry can be deconvoluted into separate single pore and pore-blocking contributions. The suggestion of pore-blocking effects has been confirmed using PFG NMR. Hence, percolation theory has been used, for the first time with cryoporometry, to analyse the pore-blocking contribution to the hysteresis to determine the accessibility function and pore connectivity of the void space of a mesoporous sol–gel silica catalyst support pellet. This work demonstrates that NMR cryoporometry can be used to obtain a full range of void space descriptors, and thus offers a full, and potentially better understood, complementary pore structure characterisation method to gas sorption and mercury porosimetry.
Journal: Chemical Engineering Science - Volume 63, Issue 7, April 2008, Pages 1929–1940