کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
158550 | 457012 | 2006 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Thermodynamic and Raman spectroscopic studies on H2+tetrahydrofuran+waterH2+tetrahydrofuran+water and H2+H2+ tetra-n -butyl ammonium bromide+waterbromide+water mixtures containing gas hydrates Thermodynamic and Raman spectroscopic studies on H2+tetrahydrofuran+waterH2+tetrahydrofuran+water and H2+H2+ tetra-n -butyl ammonium bromide+waterbromide+water mixtures containing gas hydrates](/preview/png/158550.png)
Phase equilibrium curves of H2+H2+ tetrahydrofuran and H2+H2+ tetra-n-butyl ammonium bromide mixed gas hydrates were measured in a pressure range from 0.1 to 13.6 MPa. Each three-phase equilibrium curve converges at the maximum temperature point of pure tetrahydrofuran and tetra-n-butyl ammonium bromide hydrates, respectively. The difference of maximum temperatures is about 8 K, that is, the equilibrium curve of H2+H2+ tetra-n -butyl ammonium bromide mixed gas hydrate shifts to the high-temperature side from that of H2+H2+ tetrahydrofuran mixed gas hydrate. It is directly confirmed by use of Raman spectroscopy that H2H2 is enclathrated in the hydrate cages by adding a small amount of tetrahydrofuran or tetra-n -butyl ammonium bromide. In both mixed hydrates, H2H2 is enclathrated in only the small cage while tetrahydrofuran or tetra-n-butyl ammonium bromide occupies the large cages of each mixed hydrate.
Journal: Chemical Engineering Science - Volume 61, Issue 24, December 2006, Pages 7884–7888