کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
159144 457028 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermal isomerization of αα-pinene in supercritical ethanol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Thermal isomerization of αα-pinene in supercritical ethanol
چکیده انگلیسی

The experimental study followed by mathematical processing of the data showed that supercritical ethanol is an effective reaction medium for thermal isomerization of αα-pinene. Rate of the reaction in supercritical solvent is by several orders of magnitude greater than the rate observed under normal conditions, with selectivity to the target reaction products being retained. The study allowed us for the first time to obtain the kinetic model of αα-pinene isomerization in supercritical ethanol that takes into account temperature and pressure effect on the reaction rate and selectivity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 62, Issue 9, May 2007, Pages 2414–2421
نویسندگان
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