کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
167424 1423429 2012 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Measurements of Conductivity for Low Concentration Strongelectrolytes in Organic Solvents (I) LiBr, LiCl, and LiNO3 in Alcohols
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Measurements of Conductivity for Low Concentration Strongelectrolytes in Organic Solvents (I) LiBr, LiCl, and LiNO3 in Alcohols
چکیده انگلیسی

The conductivities of LiBr, LiCl, and LiNO3 in methanol, ethanol, 1-propanol, and 2-propanol (with electrolyte concentrations <0.08 mol·L−1) were determined at 298.15 K, 313.15 K, and 323.15 K at atmosphere pressure separately by using a conductivity meter. The conductivity data were correlated with Foss-Chen-Justice (FCJ) equation and the limiting molar conductivities were obtained. The mean ionic activity coefficients of the salts in the organic solvents were calculated according to the Debye-Hückel limiting law and Onsager-Falkenhangen equations. The calculated results were compared with those activity coefficients in literature.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Chemical Engineering - Volume 20, Issue 5, October 2012, Pages 1024-1033