کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
170289 458384 2015 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sunlight-driven trifluoromethylation of olefinic substrates by photoredox catalysis: A green organic process
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Sunlight-driven trifluoromethylation of olefinic substrates by photoredox catalysis: A green organic process
چکیده انگلیسی

The principles and utility of photoredox catalysis in organic synthesis are described. After a brief description of the features of the two types of catalytic photoredox processes following the reductive quenching cycle (RQC) and the oxidative quenching cycle (OQC), the discussion is focused on organic transformations based on OQC, in particular the trifluoromethylation of olefinic substrates with electrophilic trifluoromethylating reagents furnishing solvolytic addition products and substitution products. It is concluded that catalytic photoredox systems are green from the point of view of harmfulness, safety, and energy source (visible light, including sunlight). Future prospects of photoredox catalysis will be also discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Comptes Rendus Chimie - Volume 18, Issue 7, July 2015, Pages 742–751
نویسندگان
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