کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
170382 458390 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of new pyrochlore solid solution Bi1.5Sb1.5–xNbxCuO7
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis and characterization of new pyrochlore solid solution Bi1.5Sb1.5–xNbxCuO7
چکیده انگلیسی

New pyrochlore solid solutions Bi1.5Sb1.5–xNbxCuO7 have been synthesized (0 ≤ x ≤ 1.5) via the ceramic method in the air at 1000 °C. Rietveld refinement of the compounds Bi1.5Sb1.5–xNbxCuO7 for x = 0, x = 0.75 and x = 1.5 by means of X-ray powder diffraction analysis confirmed an overall A2B2O7 cubic pyrochlore structure according to (Bi3+1.5Cu2+0.5)(Sb5+1.5–xNb5+xCu2+0.5)O7 formula with 10.42009 (3) Å, 10.47193 (3) Å and 10.52679(4) Å, respectively, and Fd3¯m space group. Composition dependencies of cell parameters show a linear increase with the niobium x fraction. The magnetic susceptibility measurements achieved between 4 and 400 K indicate a paramagnetic behavior with an oxidation state “+2” for the copper ion. The electric resistivity measured using complex impedance spectroscopy evidences an increase of the electric conductivity with temperature and niobium substitution.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Comptes Rendus Chimie - Volume 17, Issue 9, September 2014, Pages 899–904
نویسندگان
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