کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
170934 | 458423 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrothermal synthesis and crystal structure of a novel two-dimensional molybdenum(V) phosphate with manganese coordination cations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Hydrothermal synthesis and crystal structure of a novel two-dimensional molybdenum(V) phosphate with manganese coordination cations Hydrothermal synthesis and crystal structure of a novel two-dimensional molybdenum(V) phosphate with manganese coordination cations](/preview/png/170934.png)
چکیده انگلیسی
A novel two-dimensional network structure formed by molybdenum(V) phosphate and manganese coordination cations, [Mn2Mo12O30(HPO4)8(H2O)]·(NH3CH2CH2NH3)6·3.5H2O (1), was synthesized hydrothermally and characterized by single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P1¯, with a = 12.006(2) Å, b = 14.582(3) Å, c = 21.270(4) Å, α = 86.00(3)°, β = 88.00(3)°, γ = 78.00(3)°, the final R converged to the value 0.0604 for 12 917 observed reflections with I > 2σ(I). In this compound, the poly(oxomolybdophosphate) anions are interconnected by transition-metal manganese cations to form an extended two-dimensional framework where the uncoordinated ethylenediamine cations and lattice water molecules are located.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Comptes Rendus Chimie - Volume 11, Issues 1–2, January–February 2008, Pages 152–158
Journal: Comptes Rendus Chimie - Volume 11, Issues 1–2, January–February 2008, Pages 152–158
نویسندگان
Dan Wu, Shen Lin, En Tang, Guiyang Yan,