کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
171399 458456 2009 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Wire-like diruthenium σ-alkynyl compounds and charge mobility therein
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Wire-like diruthenium σ-alkynyl compounds and charge mobility therein
چکیده انگلیسی

Described in this short review is the chemistry of wire-like diruthenium σ-alkynyl species, which are promising building blocks for organometallic molecular wires. Two series of carbon-rich compounds have been studied: (a) polyyn-diyls with diruthenium capping units, and (b) bi-ferrocenes with a diruthenium alkynyl bridge. Investigations of both the charge transfer process across the polyyn-diyls and the role of diruthenium cores in enhancing charge mobility are achieved through X-ray structure determination, spectroscopic, voltammetric and spectroelectrochemical measurements.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Comptes Rendus Chimie - Volume 12, Issues 3–4, March–April 2009, Pages 321–331
نویسندگان
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